Electrical Conduction - Ohm's Law

The Beginning:



Click to enlarge          See Shocking communication

Stephen Gray, a British chemist, is generall credited with discovering that electricity can flow (1729).  He found that corks stuck in the ends of glass tubes become electrified when the tubes are rubbed.  He also transmitted electricity approximately 150 metres through a hemp thread supported by silk cords and, in another demonstration, sent electricity even farther through metal wire.  Gray concluded that electricity flowed everywhere. (reference)

The Great Enabling Technology - Alessandro Volta's "Column Battery" (~1800)



The "electromotive force" is scalable!


Quantification of Electrical Conductivity - Ohm's Law



In 1827 what is now known as Ohm's law appeared in Die galvanische Kette, mathematisch bearbeitet.   Between 1825-27, Georg Simon Ohm (1789-1854), professor of mathematics at the Jesuit College of Cologne, had been studying electrical conduction following as a model Fourier's study of heat conduction.   Ohm's Law states that the strength of an unvarying electric current is directly proportional to the electromotive force, and inversely proportional to the resistance of the circuit concerned.  Need it be said, the unit of resistance is named after him. (Reference 1 and Reference 2)


In a series of experiments in 1825 Ohm demonstrated that there are no "perfect" electrical conductors.  Every conductor he tested offered some level of "resistance."  Ohm's law of states that if temperature remains constant, the current flowing through a conductors is proportional to the potential difference (voltage) across it.  In modern words, current equals voltage divided by resistance.  In most equations and diagrams, "I" represents the current, "V" the voltage, and "R" the resistance.

Current = Voltage/Resistance

The diagram below shows exactly how Ohm's Law works with a common battery. The yellow symbol represents a current measuring device - say, a light  bulb.  The tan wire shows where the resistence occurs.

Formally, electrical resistance is the property of any object or substance to resist or oppose the flow of an electrical current.  The unit of resistance is the ohm symbolized by the Greek letter omega and the value of the electric resistance is commonly abbreviated  as R.   For certain electrical calculations the reciprocal of resistance is used, 1/R, which is termed the conductance, G.  The unit of conductance is the mho, or ohm spelled backward, and the symbol is an inverted omega.

In principle, it is relatively simple to measure the resistance of a strand of wire by connecting a battery to a wire of known voltage and then measuring the current flowing through the wire.  The problem with using resistance as a measure is that it depends not only on the material from which the wire is made, but also the geometry of the wire. If we were to increase the length of wire, for example, the measured resistance would increase. Also, if we were to decrease the diameter of the wire, the measured resistance would increase. We want to define a property that describes a material's ability to transmit electrical current that is independent of the geometrical factors.


The geometrically-independent quantity that is used is called resistivity and is usually indicated by the Greek symbol rho.  In the case of a wire, resistivity is defined as the resistance in the wire, times the cross-sectional area of the wire, divided by the length of the wire.  The units associated with resistivity are thus, ohm - m (ohm - meters). The diagram below shows this equation as it would work with a common wire, represented by the tan cylinder.


High values of resistivity imply that the material making up the wire is very resistant to the flow of electricity. Low values of resistivity imply that the material making up the wire transmits electricial current very easily.

 

The Resistivity of Several Natural Elements and Compounds


Substance
Resistivity (rho)
(ohm - meters)
Substance Resistivity (rho)
(ohm - meters)
Silver
1.59 x 10-8
Sea Water 0.2
Copper                          
1.68 x 10-8 Ground Water 0.5 - 300
Gold
2.21 x 10-8 Germanium
0.46
Aluminum
2.65 x 10-8
Silicon 640
Brass 3.5 x 10-8 Sphalerite 1.5 - 1 x 107
Sodium
4.8 x 10-8 Igneous Rock - Diabase 20 - 5 x 107
Tungsten 5.6 x 10-8 Wood 1010
Iron
9.71 x 10-8 Calcite 2 x 1012
Platinum
10.6 x 10-8
Rock Salt 30 - 1 x 1013
Lead 20.8 x 10-8 Mica 1013 - 1014
Constantan
49 x 10-8
Glass 1010 - 10 14
Stainless Steel
72.0 x 10-8 Aluminum Oxide
1011
Mercury 98 x 10-8 Silicon Dioxide
1016
Nichrome
(Ni,Fe,Cr alloy)
100 x 10-8
Rubber 1013 - 10 16


Quartz 4 x 1010 - 2 x 1014
Carbon (graphite)
3-60 x 10-5
Quartz (fused)
7.5 x 1017


Carbon (diamond)
>1015